From soft harmonic phonons to fast relaxational dynamics in CH3_{3}NH3_{3}PbBr3_{3}

The lead-halide perovskites, including CH$_{3}$NH$_{3}$PbBr$_{3}$, are components in cost effective, highly efficient photovoltaics, where the interactions of the molecular cations with the inorganic framework are suggested to influence the electronic and ferroelectric properties. CH$_{3}$NH$_{3}$PbBr$_{3}$ undergoes a series of structural transitions associated with orientational order of the CH$_{3}$NH$_{3}$ (MA) molecular cation and tilting of the PbBr$_{3}$ host framework. We apply high-resolution neutron scattering to study the soft harmonic phonons associated with these transitions, and find a strong coupling between the PbBr$_{3}$ framework and the quasistatic CH$_{3}$NH$_{3}$ dynamics at low energy transfers. At higher energy transfers, we observe a PbBr$_{6}$ octahedra soft mode driving a transition at 150 K from bound molecular excitations at low temperatures to relatively fast relaxational excitations that extend up to $\sim$ 50-100 meV. We suggest that these temporally overdamped dynamics enables possible indirect band gap processes in these materials that are related to the enhanced photovoltaic properties.Comment: (main text - 5 pages, 4 figures; supplementary information - 3 pages, 3 figures

Action Emulation

The effects of public announcements, private communications, deceptive messages to groups, and so on, can all be captured by a general mechanism of updating multi-agent models with update action models, now in widespread use. There is a natural extension of the definition of a bisimulation to action models. Surely enough, updating with bisimilar action models gives the same result (modulo bisimulation). But the converse turns out to be false: update models may have the same update effects without being bisimilar. We propose action emulation as a notion of equivalence more appropriate for action models, and generalizing standard bisimulation. It is proved that action emulation provides a full characterization of update effect. We first concentrate on the general case, and next focus on the important case of action models with propositional preconditions. Our notion of action emulation yields a simplification procedure for action models, and it gives designers of multi-agent systems a useful tool for comparing different ways of representing a particular communicative action

Epistemic Logic with Partial Dependency Operator

In this paper, we introduce $\textit{partial}$ dependency modality $\mathcal{D}$ into epistemic logic so as to reason about $\textit{partial}$ dependency relationship in Kripke models. The resulted dependence epistemic logic possesses decent expressivity and beautiful properties. Several interesting examples are provided, which highlight this logic's practical usage. The logic's bisimulation is then discussed, and we give a sound and strongly complete axiomatization for a sub-language of the logic

Action Emulation

The effects of public announcements, private communications, deceptive messages to groups, and so on, can all be captured by a general mechanism of updating multi-agent models with update action models, now in widespread use. There is a natural extension of the definition of a bisimulation to action models. Surely enough, updating with bisimilar action models gives the same result (modulo bisimulation). But the converse turns out to be false: update models may have the same update effects without being bisimilar. We propose action emulation as a notion of equivalence more appropriate for action models, and generalizing standard bisimulation. It is proved that action emulation provides a full characterization of update effect. We first concentrate on the general case, and next focus on the important case of action models with propositional preconditions. Our notion of action emulation yields a simplification procedure for action models, and it gives designers of multi-agent systems a useful tool for comparing different ways of representing a particular communicative action

Introducing a Calculus of Effects and Handlers for Natural Language Semantics

In compositional model-theoretic semantics, researchers assemble truth-conditions or other kinds of denotations using the lambda calculus. It was previously observed that the lambda terms and/or the denotations studied tend to follow the same pattern: they are instances of a monad. In this paper, we present an extension of the simply-typed lambda calculus that exploits this uniformity using the recently discovered technique of effect handlers. We prove that our calculus exhibits some of the key formal properties of the lambda calculus and we use it to construct a modular semantics for a small fragment that involves multiple distinct semantic phenomena

A Denotational Semantics for First-Order Logic

In Apt and Bezem [AB99] (see cs.LO/9811017) we provided a computational interpretation of first-order formulas over arbitrary interpretations. Here we complement this work by introducing a denotational semantics for first-order logic. Additionally, by allowing an assignment of a non-ground term to a variable we introduce in this framework logical variables. The semantics combines a number of well-known ideas from the areas of semantics of imperative programming languages and logic programming. In the resulting computational view conjunction corresponds to sequential composition, disjunction to ``don't know'' nondeterminism, existential quantification to declaration of a local variable, and negation to the ``negation as finite failure'' rule. The soundness result shows correctness of the semantics with respect to the notion of truth. The proof resembles in some aspects the proof of the soundness of the SLDNF-resolution.Comment: 17 pages. Invited talk at the Computational Logic Conference (CL 2000). To appear in Springer-Verlag Lecture Notes in Computer Scienc